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Journal Articles

H$$_{2}$$ production from methane decomposition by fullerene at low temperature

Tokunaga, Tomoharu*; Kuno, Kohei*; Kawakami, Takumi*; Yamamoto, Takahisa*; Yoshigoe, Akitaka

International Journal of Hydrogen Energy, 45(28), p.14347 - 14353, 2020/05

 Times Cited Count:2 Percentile:6.57(Chemistry, Physical)

To understand the catalytic behavior of graphite and carbon black with mainly 6-membered rings with sp$$^{2}$$ bonds for H$$_{2}$$ production by CH$$_{4}$$ decomposition, fullerenes with 6-membered rings and also those comprising 5- and 7-membered rings with sp$$^{2}$$ bonds was investigated using gas chromatography, XPS and TEM analysis. From these analysis, it is anticipated that the ring structures without 6-membered rings in carbon materials with sp$$^{2}$$ bonding contribute to the catalytic behavior for CH$$_{4}$$ decomposition at a low temperature of 400$$^{circ}$$C.

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